Youtube daily report Apr 18 2018

You're no hero

So don't act like it

And please don't treat me

Like I'm yo sidekick

Cause I watch t.v

I see how life is

And it's not easy

But still I'm right here

Screamin'

I'm good,I'm good,I'm good,I'm good

Yeah

My nigga

I'm good,I'm good,I'm good,I'm good

You're no hero

So don't act like it

And please don't treat me

Like I'm yo sidekick

Cause I watch t.v

I see how life is

And it's not easy

But still I'm right here

Screamin'

I'm good,I'm good,yeah

My nigga

I'm good,I'm good,yeah

Coming up to me

Like "you still making music,man?"

Ask them kind questions

Shouldn't even shake your hand

Though you were the homie

Still don't know me, It's so ever damn

2 Million fucking views

And growing, follow my accomplishments

I mean

Cause I do work my ass off

Back up in the game

Like my vocals got the cast off

All I've been is cast off

By those who seem to lack heart

Tryna give the world some hope

So through the dark I'll cast art

Hoping life's the way

Brightens your yesterday

Life's been dark, And y'all can see I've had a lot to say

Few friends have been supportive

You can tell by how I word it

So being round that energy

I feel I can afford it

Talking bout I need direction

Samba where is yours

I've had mine, And it's the only thing

That I've been working toward

And I built it from the floor

Y'all don't seem to help no more

See it's hard to movement

Cause the internet's what opened door

You're no hero

So don't act like it

And please don't treat me

Like I'm yo sidekick

Cause I watch t.v

I see how life is

And it's not easy

But still I'm right here

Screamin' I'm good,I'm good,I'm good,I'm good

Yeah

My nigga

I'm good,I'm good,I'm good,I'm good

Yeah

What I mean to say

Is y'all ain't been about the dream

Even back in highschool

Y'all weren't really bout the team

To those who were

You know I know

And your support means everything

Bout to prove

Come from anywhere

And become anything

That you can take whatever you love

And make it everything

What part is bigger than us

We made it everything

And you know

It's because I wear my word

Like a wedding ring

Sticking to my cray

Put honesty above everything

Cause,I ain't been perfect

But at least I got a purpose

Rising stars in my contact list

We hit beats and we merk shit

Conversation with the greatest

Can't wait to say I made it

Shouts to those who say

I helped them get through hard times

You my favourite

Shouts to channels that upload me

And the haters that can blow me

And shouts out to a world

Insists of you won't seek control me

Blogs that show me love

And friends who love what we does

Everyone who sees us hitting the before it comes

You're no hero

So don't act like it

And please don't treat me

Like I'm yo sidekick

Cause I watch t.v

I see how life is

And it's not easy

But still I'm right here

Screamin' I'm good

Yeah

My nigga

I'm good,I'm good,I'm good,I'm good

Yeah

For more infomation >> Asobi ni iku yo「 AMV 」- I'm Good - Duration: 3:33.

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Jonathan Osorio firma el empate del Toronto 1-1 ante Chivas - Duration: 1:16.

For more infomation >> Jonathan Osorio firma el empate del Toronto 1-1 ante Chivas - Duration: 1:16.

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HOW TO MAKE A PRIVATE SERVER IN GMOD IN UNDER 3 MINUTES! (How to Gmod) Ep 1 - Duration: 2:55.

Hey guys, what is up its Matthew aka HunterPlayz and today

I'm gonna be doing my first episode of How to Garry's Mod, and I'm

Gonna show you guys how to make a small little Private Server so you and your friends can play.

Just a little note that like this is not a public server

and No one that is Invited cannot join your Game

It is very easy to make and it will only take one minute, so let's go ahead and get started

So the first thing you're gonna want to do is go into start a new game

Pick any Map you want

I'm going to go to gm_flatgrass

This is where you pick how many Players, But It will be on single player and there would be nothing here.

You just want to go ahead, and pick any of these.

You can name it whatever you want.

and The reason these are set to Really high, Is because I want like infinite props and vehicles and stuff, so yeah

Right here is what you can enable

this is what I have right now

so

That's good and

Oh, yeah

Make sure it's set to peer-to-peer

If you want it it can be friends only but if it's friends only, only your friends could be invited (Why did I even say this..)

But if it's peer to peer anybody can't be invited and than start the game! I'll see you guys once I'm in the game

Okayyy..

Finally, I got in..

okay So it looks like just an ordinary just you know single-player server, but really it's it's not

um so

for example if

A friend were to join in, I have ULX, so I'm just gonna spawn in one bot because I have two players enabled

they

As you can see are able to join

if I had it to single player, I don't think any bots would be able to join and

I'd just be a loner. (lol)

So yeah guys with so that's pretty much it

and just..

Do whatever you guys do uh

Yeah, so if you guys enjoyed this video. Please be sure to leave a like down below, subscribe If you haven't already

and as Always... Don't become the Hunted... Hunt!

And that is f***ed up..

For more infomation >> HOW TO MAKE A PRIVATE SERVER IN GMOD IN UNDER 3 MINUTES! (How to Gmod) Ep 1 - Duration: 2:55.

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Sergi Roberto fue expulsado pero jugará la final de Copa del Rey - Duration: 3:20.

For more infomation >> Sergi Roberto fue expulsado pero jugará la final de Copa del Rey - Duration: 3:20.

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Jonny empató el Celta-Barça tras un doble fallo de André Gomes - Duration: 3:04.

For more infomation >> Jonny empató el Celta-Barça tras un doble fallo de André Gomes - Duration: 3:04.

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허레디테리 HEREDITARY 2차 공식 예고편 (한국어 CC) - Duration: 1:11.

For more infomation >> 허레디테리 HEREDITARY 2차 공식 예고편 (한국어 CC) - Duration: 1:11.

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Toyota Camry 2018 : prix annoncés - Duration: 2:08.

For more infomation >> Toyota Camry 2018 : prix annoncés - Duration: 2:08.

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New Hot Wheels Surprise Box April SUBSCRIPTION Challenge Accepted Super Colossal T-Rex VS Unboxing - Duration: 12:53.

Wow after we open the hot wheels challenge accepted monthly surprise box

subscription box we're gonna go ahead and launch these cars right down the

clausal t-rexes throat from Jurassic world fallen Kingdom Mattel Toys Wow

New Hot Wheels Surprise Box April SUBSCRIPTION Challenge Accepted Super Colossal T-Rex VS Unboxing

okay today outside the gates of Jurassic Park we have our drastic world fallen

Kingdom roaring super castle t-rex to help us open up the new hot meals

challenge accepted monthly subscription box all saw so this is going to be the

second one I have opened up and they are awesome

hot wheels sent me this set to review from you guys so these boxes are really

awesome these are monthly subscription boxes full of awesome Hot Wheel products

who give products before their launch a lot a lot of stuff to paint client at

the store so the first thing you get you get three feet of track so you could

build something awesome

rockwheel cyber speeder this one is not even going to be available to buy it at

the market for a few more months so you get and for the addition one here so

that is really cool since glow-in-the-dark wheels to lighten up

the track and then it comes with this awesome clamp that you could use to

build a lot different tracks and then we got some more limited edition this is

the paradox and this is a super chrome car nine of Awesome so a lot of limited

edition cars that come in these sets this is a Hot Wheels HW glow wheels this

is a power surge car it says glow-in-the-dark wheels light up the

track and then you get this awesome challenge accepted play at Tiffany book

so if you look through here it tells you all what kind of ramps you could build

out of the box itself we have run up the wall here is showing

you how to connect to Dobson to make jumps with the tracks

challenge

you got a bunch of

there's some cars you could actually color a mission kid this is a Sudoku

parking field test pause or

for a library so this is awesome and then it also

comes with an all sub t-shirt so when you up when you get when you are order

it you tell them your teacher sighs mrs. Hot Wheels challenge accepted surprises

that one is

the site

and then it comes with this cool builder step

turn kicker the neck to expand your Seuss book

Wow

it says here's what you get add this turn kicker to your system kick your

cars around the bend Wow who keep this track you could feel

that's seriously crazy and here is a bunch of track builder connect systems

awesome let's go ahead and open these cars and check them up ok so the first

thing we're gonna check out is this cyber speeder this is the one that is

new for 2018 so this one you're not even gonna see for sale for a few months Wow

check this guy out Wow check this guy out he's a really

cool purple this is the one that will have the glow-in-the-dark wheels

this says glow over there you can see this looks almost like one car from like

Tron that is really cool on the back bottom

the hot wheels this one rolls super smooth why

it's like silky smooth and then the second one we're gonna open up is the

power search

so if your hot wheels spin I mean this is like the perfect gift to give

obviously we are also so here you've got the power surge pendant a little similar

to the purple one really cool color and you glow-in-the-dark tires got like a

red and pink colour scheme to it you've got this Chrome on top we've really

amplified it back to the car chrome on the back and a really bright purple

bottom that one too super smooth rolling and then we have a super chrome one this

one is the birth so Hot Wheels fans will really like getting some of these

exclusive cars the food check that out that is awesome it's like a gold and

blue color with like a light blue all windshield the harp the seats are all

the way in the back

super oversized tires

wrong color green in sleeeeep

this one also news okay so this also has three feet of track so that would be

by four pieces of track with and actors and then you also get this

awesome

Kraft lon a lot directions

so you could use the clamps to run the track in

direction to create all kinds of jumps and everything and then you got this

cool track builder set with the turn picker so you just simply go ahead pop

the back open you have a set of instructions here this year

yeah great tracks

and that this car is its seat for everywhere you see like it's yellow

color with oversized tires says hot wheels

and orange see-through bottom basalt you get four cars and this set one of them

is an exclusive one and the other ones are really awesome okay so the turn

kicker gives your car super boost so basically you are this is how it is when

it already launches your car so you just simply pull it back here and then you

just drive one of the cars into it you don't have to push it too hard and then

it launches your car so let's try that with another car it's got a strong

rubber band there so when you drive in launches your car out the other band and

let's try the gold bar it actually can't with

and there we go okay so we're gonna use this term kicker

to actually launch the cars into the T Rexes box salt and start with Nicole

so the crack will actually just roll right into the tea break

1g

now this t-rex is actually the perfect accessory to hot wheels or Matchbox cars

because it's so big inside it'll hold 12 the about 15 to 20 Matchbox cars so you

go ahead and use the turn kicker here you kick these bars right into its

stomach again with next car

try the

and then let's go ahead and try

we if you have a good launcher this one is not quite as strong this is made war

to kick it around the corner but if you have a good launcher you can launch

these things right into the T Rexes stomach check that out that is in his

stomach and follow the track and right down his

stomach top cool let's see that up close

hahahaha and our final one and I will show you how you take them out of his

stomach so with this t-rex here you simply turn

upon the side he's got an opening here and you should go ahead and roll the

cards right out of him or if you want you could run the tracks right down the

t-rex is stomach and come out here and launch the cars right through the t-rex

out its stomach and down the track okay guys that was awesome if you're

interested in this subscription box i have a link down below the video where

you can go ahead and subscribe it to it and i also have a code that will give

you this so you guys are totally awesome if you

enjoy this videos top real sefie miss mall sompob monthly

subscription box to show you guys and I hope you guys are awesome

in today's secret word is the word

go ahead and put that in the comment section down below the video I know you

remember my club click the subscribe button below for a lot more fun video

also click the bell button to be notified every time I make a new video

click the boxes below for a lot more fun videos and if you want to see even more

go ahead and click the subscribe button

For more infomation >> New Hot Wheels Surprise Box April SUBSCRIPTION Challenge Accepted Super Colossal T-Rex VS Unboxing - Duration: 12:53.

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Morrissey: "Los locos izquierdistas modernos parecen olvidar que Hitler era de izquierda" - Duration: 2:32.

For more infomation >> Morrissey: "Los locos izquierdistas modernos parecen olvidar que Hitler era de izquierda" - Duration: 2:32.

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Five ways to protect health in winter - Duration: 4:10.

Health Network, For Public Health

Hi, you are listening to audio on mangyte.vn website

Five ways to protect health in winter

Winter is the coldest time of the year.

It is the shortest day and lowest temperature.

Because of the cold weather, it is easy to develop some illnesses for human health.

Here are five ways to help you stay healthy, and adjust to weather conditions.

1. Throw away the fatigue state.

Many people feel tired and slow in winter.

This is due to the lack of sunlight, which causes a change in the cycle of sleep, and wakes us up.

Try these tips:

Go outdoors, and acquire natural light as much as possible.

Try to sleep, and wake up at the same time every day, to get a good night's sleep.

Avoid being exhausted from exercise, or too much meditation, stress and stress, which can make you feel tired.

2. Eat more fruits and vegetables.

When it's cold and dim outside, you tend to be afraid of going to the market, and tend to eat foods that are readily available, but not good for your health.

Therefore, eating more fruits and vegetables each day, will help you maintain a healthy diet, and less feeling dull.

Eating more fruits and vegetables each day will help you maintain a healthy diet.

Winter vegetables, such as carrots, radishes, potatoes, etc. can be fried, ground or stewed into soup, hot soup for a cold winter meal, and safe for the whole family. Family.

3. Add milk.

Milk provides protein, vitamins A and B12, which help keep bones strong.

You are more likely to catch a cold in winter, so make sure your immune system is functioning properly.

Milk and dairy products such as cheese, yogurt, and so on are excellent sources of protein, vitamins A and B12, calcium, which help keep bones strong.

In winter, you should choose partially skimmed milk, or unsweetened milk, instead of pure yogurt, and whole milk.

4. Try new activities for the whole family.

Do not use cold winter months, as an excuse to stay home and rest.

Instead, go out with your whole family, try a new activity, maybe a soccer ball, or take a walk in the park or climb a mountain.

Regular exercise helps control weight, boost the immune system, and be the best way to break the stress that can build up, if your family is always in the house.

5. Enjoy a rich breakfast.

Winter is the perfect season for porridge, pho.

Eat a warm porridge bowl in the cold morning, which is a smart way to start your day.

It also boosts your intake of food, starches and fiber.

Winter is the perfect season for porridge, pho.

These foods give you energy, and help you feel more fully provided about nutrition.

If you want more convenience in cooking, oatmeal also contains a lot of important vitamins and minerals, without the need to add more food.

Add a banana or other fruit, to add flavor and help you reach your goal all day.

Mai Huong, Military Academy.

The content of this post is ending, you have questions, questions please share the comments below this article.

Please subscribe to the Health Network channel, share this article with your friends and follow up with the next audio.

Hope this article will bring you many useful things.

Wish you always healthy.

For more infomation >> Five ways to protect health in winter - Duration: 4:10.

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Mariachi México Lo Mejor de la Música Mexicana Mariachi Vargas ¡Viva México! - Duration: 1:40:25.

For more infomation >> Mariachi México Lo Mejor de la Música Mexicana Mariachi Vargas ¡Viva México! - Duration: 1:40:25.

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Noksu Funny Cartoon Show

For more infomation >> Noksu Funny Cartoon Show

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[VIDEO] LuHan - "Total Soccer" at CCTV 5 - Duration: 0:30.

Hello everyone, I am LuHan

"Total Soccer" is about pure Soccer, the highest enjoyment

Every Monday 7:30 p.m on CCTV 5. See you there!

For more infomation >> [VIDEO] LuHan - "Total Soccer" at CCTV 5 - Duration: 0:30.

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Five incredible stats following Liverpool's win over Bournemouth - Duration: 6:03.

Five incredible stats following Liverpool's win over Bournemouth

The Reds beat Bournemouth 3-0 at Anfield on Saturday as forward trio Sadio Mane, Mohamed Salah and Roberto Firmino all scored landmark strikes.

The LFC front three have now combined to score 82 of the clubs 121 goals across all competitions this term, and they dont look like stopping any time soon.

But, while Mane and Salahs strikes set individual records, Firminos low finish to complete the scoring against the Cherries brought about a club milestone.

1. The 300.

The Brazilians goal against Bournemouth was the 300th scored by the Reds during Klopps 148-game tenure.

The former Borussia Dortmund boss arrived at Anfield in October 2015 and his side now average an incredible 203 goals per game - a better rate than any Reds manager in the last 15 years.

Fittingly, it has been Firmino who has led the charge, scoring more times under the German than any other Liverpool player.

The No.9 has played more games (130) and scored more goals (48) during Klopps reign than any of his colleagues.

2. The case for the defence.

But its not just Liverpools much-vaunted attack that has been impressive this season.

The Reds limited Bournemouth to just one shot on target at Anfield on Saturday as they claimed a 15th clean sheet in the Premier League this season.

To put that into perspective, only top-four rivals Manchester United have more shut-outs in the top-flight this term with 16.

In fact, over the season, Klopps side have limited their opponents to just 94 shots on target - a miserly total beaten only by newly crowned Premier League champions Manchester City (77).

3. Mane makes history.

Sadio Mane followed up his own header to open the scoring against Bournemouth and became the highest-scoring Senegalese player in Premier League history in the process.

The former Red Bull Salzburg forward, who spent two years at Southampton before joining Liverpool in 2016, notched his 44th goal in the English top flight to overtake ex-West Ham, Newcastle and Chelsea striker Demba Ba.

Of all the players to have hit 10 or more goals in all of their Premier League seasons, only Manchester City's Sergio Aguero (seven) and Eric Cantona (five), who played for Leeds and Manchester United, have done it more often than Mane (four).

4. Gini the pass master.

Georginio Wijnaldum lined up alongside captain Jordan Henderson and Alex Oxlade-Chamberlain in a three-man midfield against Bournemouth and didnt misplace a single pass during the entire match.

The Netherlands international completed 100 per cent of his 42 passes; 21 of which came in the oppositions half, with four leading to shooting opportunities for his teammates.

Wijnaldum is only the fourth midfielder to have a 100 per cent passing accuracy in a Premier League game this season (minimum 40 passes), along with Tottenhams Mousa Dembele, Arsenals Mohamed Elneny and Swanseas Ki Sung-yueng.

5. Mo goals.

That just leaves the small matter of record-breaking goal machine Mohamed Salah.

We could have had an entire article just on the Egyptians statistics after he notched his 40th goal of the season across all competitions.

Salah has powered to that phenomenal tally quicker than any other player in the history of the club, taking  just 45 games to reach the landmark and beating George Allans record of 40 goals in 49 appearances, which had stood since 1897.

But the LFC No. 11s goalscoring exploits extend far beyond Anfield.

His 30 Premier League goals this season puts him in pole position in the race for the competitions Golden Boot, five ahead of Tottenham Hotspurs Harry Kane.

He also leads Barcelonas Lionel Messi in a closely fought contest for the European Golden Shoe.

For more infomation >> Five incredible stats following Liverpool's win over Bournemouth - Duration: 6:03.

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Link xem U19 Việt Nam vs U19 Mexico: Việt Nam sẵn sàng tạo cú sốc - Duration: 3:30.

For more infomation >> Link xem U19 Việt Nam vs U19 Mexico: Việt Nam sẵn sàng tạo cú sốc - Duration: 3:30.

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Firmino has his own style and that makes him special - Duration: 4:11.

Firmino has his own style and that makes him special

That's according to a man who displayed similar attributes during his own Anfield career: Dirk Kuyt.

A clever late strike during Saturday's 3-0 win over AFC Bournemouth took Firmino's goal tally for the season so far to 25, meaning 2017-18 already represents the most prolific campaign of the Liverpool No.9's career to date.

His 47 appearances across all competitions this term have also yielded 14 assists, and former Reds forward Kuyt is a huge fan of the Brazilian - particularly his willingness to prioritise collective success over personal glory.

"He has his own style and that makes him special," the ex-Netherlands international told Liverpoolfc.com. "That's what I like in players.

A typical goalscorer or different kind of striker, you see that a lot in Europe, but Firmino has his own style and he has his own speciality; he is scoring great goals but also feeding the players around him.

"He's a great goalscorer but he's also a team player in everything he does.

I don't know him quite well, but if I see him playing then he just wants to win with the team and he's not the type of player who wants to score for himself.

That, for me, is the biggest thing of Firmino. .

"He's scoring great goals but he's also giving great assists and then you are, in my eyes, a complete player who is a great thing for Liverpool.

"I think he's also a very hard worker, he's selfless and working hard.

I watch almost all the games and the games I see then he's always giving his everything.

Sometimes he's not scoring goals or giving assists, but for one thing he is always giving his everything.".

Mohamed Salah also reached a goalscoring landmark as Bournemouth were beaten at the weekend, with the No.

11 becoming only the third player in Liverpool's rich history to hit the 40-goal mark in a season.

But, similarly to Firmino, Kuyt believes Salah will be motivated more by helping the team accomplish their targets than individual accolades.

"Mo Salah, I think he's having a great season.

I think Firmino's having a great season and the team is doing quite well, especially over the last couple of months.

But at the end of the day, these are individual achievements and the next step for them will be to have a team achievement," he continued.

"The only thing then that matters is to win trophies and I think, from what I can see from these kind of players, they are desperate to win trophies as a team, not as an individual.

"As an individual, players like Firmino and Mo Salah are showing that they are doing really well, but now they want to achieve it as a team.

That's the next step and who knows, maybe they can do it in the Champions League.".

For more infomation >> Firmino has his own style and that makes him special - Duration: 4:11.

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Locker Room Stories - Duration: 2:22.

Whenever I asked a guy what kind of things guys talk about locker rooms, they always very uncomfortably avoid my questions.

I get it. There are things guys like to talk about when girls aren't around, and for good reason. Fine.

I don't need your lousy locker room stories. I have other sources too that.

In high school, I was the quiet invisible girl.

No one thought twice about what they talked about around me because it seems that extrovert logic--

--is that if someone doesn't talk they don't listen?

It's amazing what people will talk about around you when they think you're not listening or they just don't notice you.

When I was in high school, I thought about making a comic series about the weird and questionable things--

--I overheard while I was in the girls locker room.

Fortunately, unfortunately... I only have the one story? And have held on to this one for years.

So like, what if there was like this machine, that like, weighed to your bewbs?

Like, what if you just put your bewb on it, and you could figure out the weight of your bewbs?

What if it was like?

Shaped like a hand yeah, it's just a hand and you can just put your bewb on it, and it weighs your bewbs!

I'm a genius!

So... that happened.

Did you come here to hear a girl talk about private girly things? Congrats. I don't plan on doing that again anytime soon.

So hey, I'm actually a cartoonist and comic artist.

Did you know that? You should use your eyes to look at my real art like this, and this. Ooooooh, Aaaaaah!

You can find more of my art on my deviantART and Tumblr. I usually do fan art, so have fun with that.

BEWBS.

For more infomation >> Locker Room Stories - Duration: 2:22.

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Opel ADAM 1.2i 70PK Airco | Bluetooth - Duration: 1:10.

For more infomation >> Opel ADAM 1.2i 70PK Airco | Bluetooth - Duration: 1:10.

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Traitor! President Trump Furious With Justice Gorsuch After Shocking Verdict - Duration: 4:36.

Traitor!

President Trump Furious With Justice Gorsuch After Shocking Verdict.

In a shocking move on Tuesday, President Donald Trump's choice for the Supreme Court, Justice

Neil Gorsuch, stabbed the president in the back.

Justice Gorsuch sided with the liberal justices on the court, delivering a severe blow to

the president's policy on enforcing immigration laws.

In a 5, 4 decision, Justice Gorsuch voted along with Justices Ruth Bader Ginsburg, Stephen

Breyer, Sonia Sotomayor, and Elena Kagan, siding with an immigrant who was convicted

of residential burglary and set to be deported, Politico reported.

The dissenting votes came from the conservative side of the court, Chief Justice John Roberts

and Justices Clarence Thomas, Samuel Alito, and Anthony Kennedy.

Justice Gorsuch agreed with the liberals that the law, that allowed for the deportation

of immigrants, who have been convicted of "a crime of violence" was too vague and

therefore unconstitutional.

The decision is one that is likely to infuriate President Donald Trump, who is tough on immigration

and appointed Justice Gorsuch to the court.

"Vague laws invite arbitrary power.

Before the Revolution, the crime of treason in English law was so capaciously construed,

that the mere expression of disfavored opinions could invite transportation or death.

The founders cited the crown's abuse of pretended crimes like this as one of their

reasons for revolution," Gorsuch wrote in his concurring opinion.

"Today's vague laws may not be as invidious, but they can invite the exercise of arbitrary

power all the same, by leaving the people in the dark about what the law demands, and

allowing prosecutors and courts to make it up," he continued.

"The law before us today is such a law.

Before holding a lawful permanent resident alien like James Dimaya subject to removal

for having committed a crime, the Immigration and Nationality Act requires a judge to determine,

that the ordinary case of the alien's crime of conviction involves a substantial risk,

that physical force may be used.

But what does that mean?"

Gorsuch asked.

"Just take the crime at issue in this case, California burglary, which applies to everyone

from armed home intruders to door-to-door salesmen peddling shady products.

How, on that vast spectrum, is anyone supposed to locate the ordinary case and say whether

it includes a substantial risk of physical force?

The truth is, no one knows.

The law's silence leaves judges to their intuitions and the people to their fate.

In my judgment, the Constitution demands more," he wrote.

Justice Gorsuch's opinion, which does not seem to be in line with President Trump, does

bear a striking resemblance to a decision made by the man he has replaced on the court,

the late Justice Antonin Scalia.

That case was cited by Justice Kagan who wrote in the opinion that the 2015 case, that struck

down a similar clause in the Armed Career Criminal Act provided guidance for Tuesday's

decision.

Justice Kagan said that the 2015 decision "tells us how to resolve this case."

The case decided on Tuesday involved a legal immigrant, identified as James Dimaya, who

came to the United States from the Philippines in 1992 when he was 13-years-old.

Dimaya pleaded no contest to two charges of burglary in California and deportation proceedings

had been started by the government.

The government said that he could be deported because his crimes could be considered "crimes

of violence", that allowed him to be sent back to the Philippines.

"If the severity of the consequences counts when deciding the standard of review, shouldn't

we also take account of the fact that today's civil laws regularly impose penalties far

more severe than those found in many criminal statutes?

Ours is a world filled with more and more civil laws bearing more and more extravagant

punishments," Justice Gorsuch said.

The decision by Justice Gorsuch angered conservatives on Twitter who called him a traitor.

It does seem rather disappointing that he would side with the liberal justices.

Let's hope that the issue was the vague language of the law and that this is not an

indication of things to come.

We hired Donald Trump based on his agenda, which included cleaning up our immigration

problem.

In turn, he nominated Gorsuch, believing he supported the conservative, America First

agenda.

This ruling leaves many in doubt when it comes to Gorsuch's values.

What do you think about this?

Please share this news and scroll down to Comment below and don't forget to subscribe

USA facts today.

For more infomation >> Traitor! President Trump Furious With Justice Gorsuch After Shocking Verdict - Duration: 4:36.

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Opel Mokka X 1.4 Turbo 140pk Automaat Innovation - Duration: 1:09.

For more infomation >> Opel Mokka X 1.4 Turbo 140pk Automaat Innovation - Duration: 1:09.

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Best Attitude status video | Kadak Attitude Status | जिंदगी पर कुछ चुनींदा अनमोल विचार - Duration: 0:34.

Whatsapp Status Video

For more infomation >> Best Attitude status video | Kadak Attitude Status | जिंदगी पर कुछ चुनींदा अनमोल विचार - Duration: 0:34.

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따뜻한 마음을 담은 '하이 랩퍼 2'이병재와 같은 '쉼표'|조회수8.212.910 - Duration: 2:48.

For more infomation >> 따뜻한 마음을 담은 '하이 랩퍼 2'이병재와 같은 '쉼표'|조회수8.212.910 - Duration: 2:48.

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Tottenham can beat Manchester United and Liverpool to second - pundit - Duration: 1:55.

Tottenham can beat Manchester United and Liverpool to second - pundit

Spurs take on Brighton at the AMEX tonight looking to bounce back from Saturday's home loss to champions Manchester City.

Mauricio Pochettino's side are four points behind Manchester United in second ahead of kick-off on the south coast.

Liverpool are third but have played a game more than both Tottenham and United.

A win for the north Londoners this evening would set-up an exciting race for the runners-up place.

And pundit Proven believes Spurs will be well-positioned to claim second if they can see off the Seagulls.

"I still think Spurs can finish second.

That's not out of the realms of possibility" David Provan Provan said: "I still think Spurs can finish second.

That's not out of the realms of possibility.

"Win tonight and they're level with Liverpool, they're right on United's shoulder.    "I said we'd expect better from Brighton but I certainly expect more from Spurs."  .

For more infomation >> Tottenham can beat Manchester United and Liverpool to second - pundit - Duration: 1:55.

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Gai sinh dục: triệu chứng, hình ảnh và cách phòng ngừa | Phòng Khám Phú Cường - Duration: 11:46.

For more infomation >> Gai sinh dục: triệu chứng, hình ảnh và cách phòng ngừa | Phòng Khám Phú Cường - Duration: 11:46.

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'Higher Wrapper 2'프로듀서가 제작 한 'Groovy Room'|조회수8.212.910 - Duration: 4:09.

For more infomation >> 'Higher Wrapper 2'프로듀서가 제작 한 'Groovy Room'|조회수8.212.910 - Duration: 4:09.

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'복싱 금메달'을 수상한 '하이 엔드 래퍼 2'|조회수8.212.910 - Duration: 2:40.

For more infomation >> '복싱 금메달'을 수상한 '하이 엔드 래퍼 2'|조회수8.212.910 - Duration: 2:40.

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ДЛЯ ЛЕВШЕЙ. ВЯЗАНИЕ КРЮЧКОМ. КАРДИГАН. РАЗБОР УЗОР+СХЕМА+ВЫКРОЙКА - Duration: 16:40.

For more infomation >> ДЛЯ ЛЕВШЕЙ. ВЯЗАНИЕ КРЮЧКОМ. КАРДИГАН. РАЗБОР УЗОР+СХЕМА+ВЫКРОЙКА - Duration: 16:40.

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ये है इश्क इश्क | Superhit Sufi Qawwali | Yeh Ishq Ishq Hai Ishq - Duration: 23:28.

Yeh Ishq Ishq Hai Ishq

For more infomation >> ये है इश्क इश्क | Superhit Sufi Qawwali | Yeh Ishq Ishq Hai Ishq - Duration: 23:28.

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Opel KARL 1.0 75pk Edition | Apricot Pink - Duration: 1:04.

For more infomation >> Opel KARL 1.0 75pk Edition | Apricot Pink - Duration: 1:04.

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Opel Mokka X Online Edition 1.4T 140pk | Navi - Duration: 1:08.

For more infomation >> Opel Mokka X Online Edition 1.4T 140pk | Navi - Duration: 1:08.

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Opel KARL Innovation 1.0 75 pk - Duration: 1:12.

For more infomation >> Opel KARL Innovation 1.0 75 pk - Duration: 1:12.

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Opel Mokka X Online Edition 1.4 Turbo 140pk | Navi - Duration: 1:09.

For more infomation >> Opel Mokka X Online Edition 1.4 Turbo 140pk | Navi - Duration: 1:09.

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J.i.d | Kendrick Lamar | Drake...

For more infomation >> J.i.d | Kendrick Lamar | Drake...

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Jonathan Pitre's mother, Tina Boileau, talks about her son: 'I don't know how to live without him' - Duration: 4:09.

Honestly, it's hard to believe that he's really gone.

I mean, every morning I wake up, or in the night, I wait to hear his voice.

It's been quite different.

I'm very used to having a very, very busy life with him, doing dressings and just being there with him.

But not having him there … I lost a big part of me. So it's been really hard.

And coming back into a life that I haven't been a part of for the past two years …

a lot of changes, a lot of getting used to.

And it's trying to find what is my normal now.

Some people have written me comparing him to Terry Fox.

I've told that to Jonathan once.

"You're kind of like the Terry Fox of our days."

And he was so humbled that he was like "No, I'm not."

But I'm like, "Look around you. You really are."

I mean, he's my hero, in a different kind of way.

He still managed to do kind of like Terry Fox's work.

Cancer affects everyone. Everybody is affected.

EB doesn't affect everyone, so it's a lot smaller.

But the amount of people that know about EB now -- everybody in Canada knows about EB, almost.

You don't have any second thoughts about going to Minnesota.

That's what Jonathan, I mean, he wanted to take the chance to have a normal life.

Jonathan wanted to live.

We had done many, many attempts to improve his quality of life before deciding to go through the BMT.

And he was a big decision-maker in his care.

At that point, he was old enough to be a big voice.

He decided that that's what he wanted and I was going to help him get there...

and go through everything that he's he's gone through in the past two years.

It was our biggest chance.

I know in my heart that if we wouldn't have done that, he would probably have passed away a little while ago.

He was quite sick before we left.

The BMT did work

I was leaving certain areas of his body uncovered … I hadn't done that since he was very, very little.

It did work and he was feeling so encouraged by it.

He wanted to learn how to ride a bike.

He wanted to just enjoy spending time with his dog, being able to walk, going back to school – very typical things that we've always done.

Most of us have had the opportunity to do without thinking twice that it was a luxury.

He had such big aspirations for when he did get home.

Things really changed.

How has Gibson adjusted to not having Jonathan here?

He knows that his buddy's gone.

He knows that something is different.

He's sniffed me. I'm sure he can smell him on me because I brought back the clothes that I had in Minnesota, so they probably smell like Jonathan.

That was the clothes I had with me.

It's hard. That was one of my biggest challenges when I got back home was to see Gibson,

because I knew that I was coming back and his buddy wasn't there.

And Jonathan just wanted to see his dog.

'You drove back from Minnesota. Can you tell us why?

I needed those days to be able to cry if I wanted to, laugh, if I wanted to, be able to talk to him, listen to music or be angry that he left me ...

and tell him that he wasn't supposed to leave – that we were supposed to get home together.

I knew that once I got back to Canada I had to face everyone, and not having him with me

You had a small service for Jonathan last week

Yep, it was very, very small. It was just for his immediate family.

(His sister) Noémy hadn't seen him in a very long time.

That's what he would have wanted.

Jonathan had two things that he really wanted to do when he got home – to see his dog and have a little bit of a family gathering.

I couldn't bring him to the family, but I brought the family to him.

For more infomation >> Jonathan Pitre's mother, Tina Boileau, talks about her son: 'I don't know how to live without him' - Duration: 4:09.

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Families For Safe Streets [TW: Child Loss] | I Am Scary Mommy | Scary Mommy - Duration: 7:03.

- Ariel was very independent.

She just loved to bake

and dance and draw and run.

My four-year-old daughter was walking

to school hand-in-hand with my mother

June four, 2013

and there was a speeding driver

who drive up onto the sidewalk

and hit both of them.

When I got into the emergency room,

my husband was punching all the hand sanitizers

off the wall, and I knew what that meant.

You know, they tried everything,

and she just didn't make it.

She was just too small.

- The loss of a child is really just

every parent's worst nightmare

and it is worse than anyone can imagine.

I lost my son four years ago

from a reckless driver.

He lived a few hours, but they were not able

to save him, so the last words he said

to me were, "I love you, Mommy."

I was just enraged, and I don't know

where I got the idea, but I borrowed a radar gun

and I went outside and I clocked the speed

of every car going by

and in a two-hour period, not a single one was

obeying the speed limit.

This is really outside of my comfort zone.

I am not a comfortable public speaker.

I am innately more of shy person,

but, you know, another mom in the group said

to me, "The worst thing in your life

"already happened.

"What've you got to lose?"

- When Amy Cohen reached out to me,

she said, "I know your story,

"I know about Ariel, and I was wondering

"if you wanted to join us.

"We're going to Albany because we are demanding

"that the speed limit in New York City be decreased."

Immediately I said yes.

This is the right thing to do.

When I speak to elected officials,

I speak to them as a parent

speaking to another parent.

They all have pictures of their families

in their office, and that's the bond

that we have.

And for the first time, it's not just a number,

just a statistic, but actually a mother

with a picture of a child who was lost.

- [Protestors] Our streets.

Whose streets?

Our streets.

Whose streets?

Our streets.

Whose streets?

Our streets.

Whose streets?

Our streets.

- We're here tonight because our hearts are broken.

We are here tonight

to demand action

because these were preventable deaths

and because these were not the only children we have lost.

- The rally in Park Slope,

it was inspiring to see so many children leading

and it made me feel

hopeful and

it made me remember that

the young people are our future.

I will go out and I will advocate

and educate and

the drivers who I think will really change are

these kids right here.

- [Protestors] Whose streets?

Our streets.

Whose streets?

Our streets.

Whose streets?

Our streets.

- Speeding, driving aggressively,

people joke about it, but it is not funny.

It is killing someone here in New York City

nearly every single day.

- There's like a brand,

there's like this cool image

that goes with driving fast and

driving violently.

My husband, when he drives, he drives

like his daughter died, right?

Because she did.

I don't wanna say drive like your child died here,

so drive like your child lives here.

- [Protestors] Not one more!

Not one more!

Not one more!

Not one more!

- Here in New York, most bills take

ten, 15 years before they pass.

We went to Albany

20 times, busloads with children,

with parents, and in one legislative session,

we passed a bill to lower the speed limit

in New York City.

People say it's unheard of.

A year after my son died,

we had lowered the speed limit,

the signs were everywhere on my street

to drive 25 miles per hour,

and a five-year-old boy was struck

in the exact same location as Sammy.

That driver was going 25

and that boy lived.

Five miles per hour is the difference

between life and death.

- Right now we are trying to get

speed safety cameras in front of schools,

because we got the speed lowered

but now we need the cameras to enforce that.

Also prosecuting violent drivers and

street redesign is a very big initiative for us,

changing the way the streets are

to protect pedestrians.

When everything first happened,

I feel a little bit like

I was the only person in the world

who was feeling this huge

gash in my heart.

Meeting this other mothers,

it really made me realize

that there are other mothers

who know this pain

and who get up every day and

put one foot in front of the other,

not just to go on but to honor

your child.

- Mothers can make a difference.

Mothers who are scary and mad can come together

and say, "Enough is enough."

My name is Amy Cohen.

- I am Sofia Russo.

- And I am a scary mommy.

- I am a scary mommy.

For more infomation >> Families For Safe Streets [TW: Child Loss] | I Am Scary Mommy | Scary Mommy - Duration: 7:03.

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Asobi ni iku yo「 AMV 」- I'm Good - Duration: 3:33.

You're no hero

So don't act like it

And please don't treat me

Like I'm yo sidekick

Cause I watch t.v

I see how life is

And it's not easy

But still I'm right here

Screamin'

I'm good,I'm good,I'm good,I'm good

Yeah

My nigga

I'm good,I'm good,I'm good,I'm good

You're no hero

So don't act like it

And please don't treat me

Like I'm yo sidekick

Cause I watch t.v

I see how life is

And it's not easy

But still I'm right here

Screamin'

I'm good,I'm good,yeah

My nigga

I'm good,I'm good,yeah

Coming up to me

Like "you still making music,man?"

Ask them kind questions

Shouldn't even shake your hand

Though you were the homie

Still don't know me, It's so ever damn

2 Million fucking views

And growing, follow my accomplishments

I mean

Cause I do work my ass off

Back up in the game

Like my vocals got the cast off

All I've been is cast off

By those who seem to lack heart

Tryna give the world some hope

So through the dark I'll cast art

Hoping life's the way

Brightens your yesterday

Life's been dark, And y'all can see I've had a lot to say

Few friends have been supportive

You can tell by how I word it

So being round that energy

I feel I can afford it

Talking bout I need direction

Samba where is yours

I've had mine, And it's the only thing

That I've been working toward

And I built it from the floor

Y'all don't seem to help no more

See it's hard to movement

Cause the internet's what opened door

You're no hero

So don't act like it

And please don't treat me

Like I'm yo sidekick

Cause I watch t.v

I see how life is

And it's not easy

But still I'm right here

Screamin' I'm good,I'm good,I'm good,I'm good

Yeah

My nigga

I'm good,I'm good,I'm good,I'm good

Yeah

What I mean to say

Is y'all ain't been about the dream

Even back in highschool

Y'all weren't really bout the team

To those who were

You know I know

And your support means everything

Bout to prove

Come from anywhere

And become anything

That you can take whatever you love

And make it everything

What part is bigger than us

We made it everything

And you know

It's because I wear my word

Like a wedding ring

Sticking to my cray

Put honesty above everything

Cause,I ain't been perfect

But at least I got a purpose

Rising stars in my contact list

We hit beats and we merk shit

Conversation with the greatest

Can't wait to say I made it

Shouts to those who say

I helped them get through hard times

You my favourite

Shouts to channels that upload me

And the haters that can blow me

And shouts out to a world

Insists of you won't seek control me

Blogs that show me love

And friends who love what we does

Everyone who sees us hitting the before it comes

You're no hero

So don't act like it

And please don't treat me

Like I'm yo sidekick

Cause I watch t.v

I see how life is

And it's not easy

But still I'm right here

Screamin' I'm good

Yeah

My nigga

I'm good,I'm good,I'm good,I'm good

Yeah

For more infomation >> Asobi ni iku yo「 AMV 」- I'm Good - Duration: 3:33.

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Opel ADAM 1.2i 70PK Airco | Bluetooth - Duration: 1:10.

For more infomation >> Opel ADAM 1.2i 70PK Airco | Bluetooth - Duration: 1:10.

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La frequenza dei pasti per i cani: ecco come comportarsi - Duration: 2:12.

For more infomation >> La frequenza dei pasti per i cani: ecco come comportarsi - Duration: 2:12.

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Toyota Yaris 1.3 VVT-i Now - Duration: 1:07.

For more infomation >> Toyota Yaris 1.3 VVT-i Now - Duration: 1:07.

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Jacques Genin Master of His Craft - Duration: 1:32.

I'm publishing this video about brilliant chocolatier Jacques Genin

because since my former video on him,

chocolate and pastry chef Jacques Genin has won a huge award.

It was presented for the whole of his work

and is highly prestigious in France for food professionals.

The few who receive the Meilleur Ouvrier de France Award

are given their medal at a ceremony held at the Sorbonne.

Also, since that former video about Monsieur Genin,

he opened a new boutique on rue du Bac,

in the general section of Paris where the Musée d'Orsay is.

There, you'll find his fabulous chocolates and on some days his pastries.

But if you prefer to eat them where he has a tea salon,

you'll need to go to Monsieur Genin's other boutique

at 133 rue de Turenne where he has a tea salon in the same building as his chocolates.

Among Monsieur Genin's house made candies,

the candied jellies and caramels nature are some of my favorites.

If you want to do something else while you're in the area

walk down rue de Varenne to the Rodin Museum.

For a mere 2 euros you can linger in a fabulous garden dotted with sculptures.

For links to some of my other videos, look below this video screen.

For more infomation >> Jacques Genin Master of His Craft - Duration: 1:32.

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GOOGLE PICKS MY MAKEUP CHALLENGE | CRUELTY-FREE 🐰 - Duration: 5:46.

I've been seeing this challenge make its rounds around YouTube so I thought I

would go ahead and give it a try because why not look like a lot of fun. My name

is Chris if you are new to my channel definitely consider subscribing if you

are into cruelty free beauty so I definitely hit that subscribe button and

the little notification bell to be notified when I upload more videos like

these! Now that I think about it it's been a little bit since I've done a challenge

so this will be really really fun. This is the Google picks My Look challenge I

believe Nikki started it? I'm sure you guys - if you're in the beauty realm you

know what I'm talking about. So let's get started I got a really

interesting picture it looks like the Sims... it looks like a Sim look. There's a

lot of blacks, browns, and white. So let's get started

I'm going to just right off the bat slather my face with a foundation so

this is the vapor organic beauty foundation I'm just gonna go ahead and

slap that on. I will definitely try my hardest to make it like a look that I

will wear but... alright right foundation applied, bam. Because there is a lot of

brown I'm going to be very intense with my contouring and this is the milk

makeup blaze matte bronzer. Really layer on that color. I think would add

just a little bit more color because I want it to be more intense. Okay I've got

the base done now let's start up with the eyes I'm gonna use this well people

bio brightener stick I'm going to use it in my or on my lids because this is

probably the only light like close to white thing that I have actually now

that I'm on it I'm just gonna highlight my face - oh I didn't blend out my nose

contour whoops hold on let's continue blend out this highlighter right, while

that sets a little bit I'm going to go in and do my brows. Hmm like they're

these little I think there's some characters they have like really thick

brows so I'm just I'm gonna I'm gonna go thicker than I normally would

cuz why not all right they don't match but that's

okay so because there's a lot of black in it

I've only felt like you would be fitting to have a black eye shadow so we're

gonna go ahead with this pixie it's Judy time palette and this is called night

night we're just going to go in the outer corner and kind of like smoke it

out. I wish I had white eyeshadow or like something that I can just draw like a

white line like they have in their clothes I believe they have yeah like

there are Addidas and they have like sportswear I wanted to draw like a white

line across my eye like that would be cool all right I'm going to add some

Brown in here I'm gonna do this color which is dark chocolate and when I just

use that as a transitional color like right above the black alright I'm going

to go in with eyeliner I'm going to make it a very straight line because I feel

like all of these have all these figures are I don't know they just seem very

rigid so I think that would be my interpretation of it so

I did not do a good job of blending my eyeshadow also I think putting the

highlighter underneath really messed that plan up I'm going to curl my lashes

and then apply some falsies. Success!

Oh god that definitely took some concentration oh I'm going to go back in

with this color palette and use bubbly this champagne-y color and highlight

the inner corners of my eyes kind of like to pull in that whole like glow

that they've got going on with these little character things. Alright and for

the lips I'm actually going to go for a bold lip this is Em cosmetics Spanish

earth I feel like this will tie in the brown like the a lot of a tan color that

they've got going on here wish me luck because I'm so bad at applying lip dark

lip colors

okay so this is it this is the finished look I feel like I kind of got lucky

with the imagery because I feel like the makeup itself it for the characters is

kind of like the makeup that I'm wearing right now but yeah I hope you guys

enjoyed watching this do hit that subscribe button if you've made it this

far and you like this video so yeah definitely do if you haven't already

well how do you guys feel about it yay nay would you wear this I wouldn't

wear this personally this isn't my look this isn't my style but I think this is

a fun challenge to definitely try something a little bit new. uh so yeah

well time to wash this off now I hope you guys enjoyed watching Oh what is my

hair doing. Okay see you in the next video. Bye!

For more infomation >> GOOGLE PICKS MY MAKEUP CHALLENGE | CRUELTY-FREE 🐰 - Duration: 5:46.

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ये है इश्क इश्क | Superhit Sufi Qawwali | Yeh Ishq Ishq Hai Ishq - Duration: 23:28.

Yeh Ishq Ishq Hai Ishq

For more infomation >> ये है इश्क इश्क | Superhit Sufi Qawwali | Yeh Ishq Ishq Hai Ishq - Duration: 23:28.

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Sharam Diniz VLOG #11 "Midnight Sun" Movie Premiere - Duration: 7:43.

For more infomation >> Sharam Diniz VLOG #11 "Midnight Sun" Movie Premiere - Duration: 7:43.

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420 Chill'n on The Mookie Show S2,E86 Tue's Quickie - Duration: 8:41.

For more infomation >> 420 Chill'n on The Mookie Show S2,E86 Tue's Quickie - Duration: 8:41.

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ONRAID - Duration: 30:38.

For more infomation >> ONRAID - Duration: 30:38.

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Question 7 Multistep Synthesis of Cinnamic Acid - Duration: 14:39.

Exam three number seven is the synthesis of cinnamic acid starting with benzene and it's

based on a homework problem and a couple of examples from our chapter and so if we look

at the opening box we have the option of only using reagents that contain two or fewer carbons

and we're limited to three up to three additional steps here for our second set of reactions,

but we got a couple of options to get to benzaldehyde so if we remembered from our reading a particular

reaction, the Gatterman-Koch reaction where we could take carbon monoxide, HCl under high

pressure and an aluminum chloride copper one chloride catalyst mixture, we could do this

all in one step and so each part of this the carbon monoxide, the HCl, the pressure and

the catalyst one point each for a maximum total here four points okay or we could have

used the alternative option also worked as an example in our reading where we have to

start with a Friedel-Crafts reaction to form a methyl benzene and then or toluene

excuse me and then we have bromine and light to brominate this position we could also have

used NBS and light or we could have used NBS a peroxide and heat as well for this step

two and then we could take that primary halide and replace it with an alcohol via a SN2 reaction

okay so that's a good candidate even though hydroxide is a strong base it's a primary

halide it'll prefer to go SN2 and then finally we could oxidize this up with sodium hypochlorite

in acetic acid at zero degrees okay I would allow in case we don't really understand or

have the knowledge of chromates and chromic acid in pyridines and chlorochromate taking

this species all the way up to benzoic acid that's something that we would not have normally

encountered so would allow PCC as well alternatively you could propose the Swern oxidation as well

each of these being worth an additional of one point each each of these four steps, but

this step four we could have alternatively used PCC or the Swern oxidation which would

involve dimethyl sulfide, oxalyl chloride at low temperature it's negative 60 degrees

followed by a workup with triethylamine so we could have used those options as well though

in practice PCC would not be a good option okay, but again it would be a good thinking

on your part to think of it as a gentle oxidizing agent, now alright so from here with benzaldehyde

we're allowed three additional steps to form cinnamic acid so based on the homework problems

and what we've seen in the chapter I can think of four ways that we can potentially do this

the two from the assigned homework problems are the malonic ester starting material and

the Perkin Synthesis which actually uses an anhydride across aldol with an ester hydrolysis

and across aldol with an oxidation of these I could see these three satisfying the requirements

of the problem and out of these three all three of these would be accepted the two in

the middle would actually work and the fourth would not work for a reason that we are not

aware of at this level of organic chemistry so let's talk about all four of these and

talk about what is going on so with a malonic ester we would be starting with a for synthesis

of a carboxylic acid that's something that the malonic ester is designed to do we would

have to have a starting material of a malonic ester and if we look at this it's got one,

two, three, four and five carbons at the minimum and if we try to make this from simpler materials

the very best we could do would be an enolate of an ester with a carbonate type species

here so that we could end up with our attack here tetrahedral intermediate kick off on

the methoxide we'd have our malonic ester the problem is each one of these has at least

three carbons each so we have to get rid of this one as one of our homework problems that

does make exactly cinnamic acid because of the carbon requirement and so that leaves

us with anhydrides and the Perkin synthesis and so let's have a look at that one okay

if we look at our starting material being acetic anhydride it's got four carbons, but

we could make acetic anhydride from a two carbon carboxylic acid okay materials containing

two carbons or less two of those would form an acetic anhydride with heating or with the

addition of a water removing agent like phosphorus pentoxide okay so we can satisfy the two carbon

requirement using this synthesis so let's look at that one first first thing up we would

need to make our anhydride using one of our steps we're limited to three, we could do

this just by heating or we could do it with the catalyst phosphorus pentoxide okay and

we would remove water in that method now from there as the homework problem would suggest

we use acetate to prevent the destruction so acetate is the carboxylate here sodium

acetate would work we can use acetate to prevent the destruction of our anhydride if acetate

attacks acetic anhydride just makes acetic anhydride and acetate right back so no problem

there we use that to form our enolate so ultimately in equilibrium we would form an enolate with

an alpha carbanion form that would be here and that could attack our benzaldehyde if

we add these three in solution okay so that enolate attacks benzaldehyde and it would

undergo spontaneous condensation to form this intermediate structure and so this should

look very familiar just like an aldol condensation just using acetic anhydride as a starting

material instead of an aldehyde or ketone so just like we saw in the book and then finally

also a homework problem portion is adding water to do the hydrolysis of this we could

also have used aqueous acid H3O plus to make sure we're in the protonated cinnamic acid

form in the final product so one step two step and three step gets us to cinnamic acid

okay so that's if we're using the Perkin synthesis like the homework problem, however, we could

also think of using a crossed aldol followed by ester hydrolysis so let's look and see

how that would look to us here if we are thinking backwards so this is not in any one of the

problems, but it's something you might have come up with if you're thinking backwards

allow me to use pH here as phenol to abbreviate this to make it a little faster we can imagine

the hydrolysis of an alpha beta unsaturated ester even though it would attack in the beta

position ultimately the final product of basic saponification or acidic hydrolysis would

be cinnamic acid in this through a series of mechanistic steps so we don't need for

this problem just hydrolyze the ester you could work that out you could have worked

that out, but hydrolysis of an ester is given in this form in our chapter so hydroxide or

with H3O plus okay to get to that ester we would have to have our say we're using a methyl

ester our methoxide and our aldehyde and then we would drip in this ester slowly and we

could form our beta-hydroxy ester that would be spontaneously

decompose or dehydrate into our alpha,beta-unsaturated ester we could also have used LDA addition

as well to get this to go, but since this doesn't have any alpha hydrogens we were able

to accomplish everything in just two synthetic steps since our process here would go all

the way to the alpha,beta-unsaturated ester so we're limited to three steps if you thought

of it as requiring three steps you could have used this as one of your steps maybe even

put heating there to indicate that dehydration and that's fine we could make this into exactly

three steps if we used LDA addition and so let me show you that as well well we're getting

a little long here, but we gotta make sure we understand this you can scrub ahead if

we're taking awhile and so let's have a look if we were to take our starting material or

excuse me we want our ester sorry our ester we could treat this with LDA this would make

our enolate of the ester and then we could add our compound slowly

to form our alpha,beta-unsaturated alkoxide here and then we could make our third step

adding a proton source to this okay and then we would end up with a spontaneous dehydration

and then we could treat it with hydrolysis conditions in order to proceed to the final

product so we could have done that as well for exactly three steps for our synthesis

now the last way we could perceive of doing this would be in a cross aldol we just did

a crossed aldol with an ester here adding to an aldehyde now let's do a crossed aldol

with the ketone adding and so we could say using acetic acid or excuse me acetone we

can say let's add LDA to make our enolate and then there's our first step let's add

benzaldehyde slowly to form here our alpha,beta-unsaturated system,

ah but then we would need two steps to protonate and then oxidize up the aldehyde so we can't

get there in four steps if we're using LDA, but what we can do instead is to a solution

already containing hydroxide we could add our ketones slowly and encourage the formation

directly of our unsaturated aldehyde this is just an aldol condensation with spontaneous

dehydration so that's one step and that's a proper a slow addition of the ketone as

well because we don't have any alpha hydrogens on our benzaldehyde okay so that's perfectly

legal and here's the part that we may or may not have thought of we could attempt to oxidize

our aldehyde with chromic acid and heat to the carboxylic acid okay and so if we do that

if seems like it should work, but in practice this goes all the way to benzoic acid and

so in reality it doesn't work however we don't know that that's beyond our study at this

point so for you to understand that the harsh oxidizing conditions to go to the carboxylic

acid here I'm okay if you use this route.

For more infomation >> Question 7 Multistep Synthesis of Cinnamic Acid - Duration: 14:39.

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PT Hotel | Garry's Mod - Duration: 18:47.

C7: Hello everyone. My name is Crow_Se7en

C7: Welcome to Garry's Mod. This map called, "PT... Hotel? PT Night?" I don't remember

C7: This is similar to the PT games Kenny: Yeah, it's PT Hotel

C7: I like to play the PT games. It's really cool

C7: Oh right! Say hello to Kenny Kenny: Hello everyone, we're back

Kenny: We haven't played Gmod for one or two months

C7: Garry's Mod doesn't have a lot of new horror maps

Kenny: Maybe, they don't make a lot of maps anymore but they're still working on it

C7: This map is new. It's the only one good map. The other maps are alright...

C7: The new maps have like 2, 3, or 3 and half stars. This maps has like 4 stars

Kenny: 4 stars

Kenny: Let's see if this map is good or not

C7: Maybe, this is the creator's first map. That means this map will be very short. Finish it like two minutes

C7: I hope not

Kenny: You don't know.. It has 4 stars

C7: I don't know. I didn't read the comments

Kenny: Same

C7: Shall we begin?

Kenny: I will go first

C7: Look at the hole in the wall

Kenny: What happened?

C7: That reminded me when I was the first person to get our dorm room on the first day

C7: And there was a hole in the wall! First day! Right there!

C7: There is a hole!

Kenny: Yeah, I remember that. It was our second year

C7: It was in 2015

Kenny: Joey thought I did it and I was like no!

C7: That means you were angry and punched the wall

Kenny: No, I can't make a big hole in the wall!

C7: Posters!

Kenny: Same thing... Nothing new

Kenny: An old-fashioned radio

C7: Someone left their Chinese food

Kenny: Pee in the bottle

C7: Oh really? How did you know?

C7: Does it look like a pee bottle?

Kenny: Color...

Kenny: You don't know if that's orange soda

Kenny: Oh true C7: I mean warm orange soda

Kenny: This view is okay...

C7: Is that what this hotel look like?

Kenny: If you visit the hotels in NYC or Montreal C7: Fair enough

Kenny: I went to Montreal and the hotel looked like this one

C7: I can't imagine if we can see naked people in these rooms

Kenny: Yeah, that. I will be like Oh... Interesting...

C7: Oh great. It's locked

Kenny: Why is it locked?

Kenny: There is nothing in this room

Kenny: Come here

Kenny: Close the door. I'm curious

Kenny: It's nothing

C7: Ooooh, we're walking in circles

Kenny: Oh right. This is PT

Kenny: I see two orange soda C7: MOVE!

Kenny: I mean club soda

Kenny: We saw orange soda and one blue can. Now, there are three blue cans

C7: I remember there was one can. Now, there are three cans

Kenny: They just added two cans

Kenny: Maybe this door is open

Kenny: Thought so! C7: Bathroom!

Kenny: Gasp, what happened?

C7: I just saw the crowbar on the floor and you took it

Kenny: I already have it

C7: The crowbar was on the floor and you took it!

Kenny: I... Never mind

C7: How can I protect myself?

Kenny: Maybe, "next round"

C7: It won't happen. Let me check the menu

C7: Ok good. I'm fine

Kenny: Thought so

Kenny: It's locked. Did you hear something?

Kenny: It sounds like moan

Kenny: Sounds like someone is moaning

C7: Shut up!

Kenny: Shut up!

Kenny: Nothing? Much better. F*** you

Kenny: Oh really? The cabinets

Kenny: And boxes C7: I see the vent

C7: Go to that door. Open it first

C7: Ok, never mind

Kenny: Look at this

Kenny: You hate the red lights

C7: Go to that door

C7: Wait, check that door

Kenny: Now, this is getting interesting

C7: Look at the floor

C7: There are the dead bodies under the floor

Kenny: Yeah shit

Kenny: Yeah, look outside the window

C7: Found the key!

Kenny: Ok hold on. Who will sleep on the wooden bed?

C7: Our farm friend

Kenny: Oh true

C7: I swear to god... You missed it

C7: There was a guy like this

C7: Poof then he's gone

Kenny: Dead bodies...

C7: Watch out... Watch out, don't fall down

Kenny: Oh, this is different now

Kenny: Boxes C7: More boxes!

C7: There is nothing here

Kenny: That's really clever

C7: Run. Move

Kenny: Found the key

Kenny: Too far

C7: This is PT

Kenny: Hello

C7: The picture is gone

C7: I don't see anything

C7: Go downstairs

Kenny: It's really hard to see anything

C7: The ladder! Go upstairs

Kenny: Oh no

C7: Please don't tell me this game is over because we're outside now

Kenny: Hope not

C7: A car! When we get in the car then the game will be over

Kenny: It said it needs a key

C7: Go upstairs

Kenny: The paint can just land perfectly

C7: Found the key

Kenny: I just go the shotgun, SMG, and ammo. I got the SMG

C7: What are you doing? Get over here!

C7: I can't open it

Kenny: Are you done?

C7: Go upstairs again?

Kenny: We don't know...

C7: Need to open that door

Kenny: The door is just open

C7: The end

C7: Is it over?

Kenny: That's not bad

C7: No post scene credit?

Kenny: This is not bad

Kenny: I hear the music play

Kenny: I guess it's over

Kenny: Thank you for watching. Please subscribe, like, or whatever

C7: Thank you for watching. Please click Subscribe, Like, Share, or whatever that will help me a lot

C7: See you in the next video

For more infomation >> PT Hotel | Garry's Mod - Duration: 18:47.

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부부의 날 가정통신문에 "성적으로 만족 주는 아내" 적은 유치원 - Duration: 5:37.

For more infomation >> 부부의 날 가정통신문에 "성적으로 만족 주는 아내" 적은 유치원 - Duration: 5:37.

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'물벼락 갑질' 사태 후 한진그룹株 시총 3천200억원 감소 ♥ 오늘의 뉴스 - Duration: 7:42.

For more infomation >> '물벼락 갑질' 사태 후 한진그룹株 시총 3천200억원 감소 ♥ 오늘의 뉴스 - Duration: 7:42.

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Don't Be Like Me - Duration: 0:50.

Hi. I'm Meena Kestirke and I'm a procrastinator. I found out about

critical illness insurance about two years ago, but I didn't sign up

immediately. And when I did it was too late for me to get the best, cheapest

coverage. I had developed a symptom from a medication and that meant that the

insurance company didn't feel comfortable covering me at the higher

level, just in case the minor symptom turned into something major. So don't be me.

Also the sooner you sign up, the cheaper

it's going to be and likely the better coverage you're going to get. It's the

kind of thing you really want to do when you're healthy and not delay.

For more infomation >> Don't Be Like Me - Duration: 0:50.

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Protikuřácké tažení: Od 1. máje si nezapálíte už ani na LetištiVáclava Havla! - Duration: 1:17.

For more infomation >> Protikuřácké tažení: Od 1. máje si nezapálíte už ani na LetištiVáclava Havla! - Duration: 1:17.

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Fuga surpreendente no Barça: saída que deixa Leo Messi furioso - Duration: 5:00.

For more infomation >> Fuga surpreendente no Barça: saída que deixa Leo Messi furioso - Duration: 5:00.

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세월호 다큐 '그날, 바다' 감독이 내레이션해준 정우성에 감동한 사연 - Duration: 3:31.

For more infomation >> 세월호 다큐 '그날, 바다' 감독이 내레이션해준 정우성에 감동한 사연 - Duration: 3:31.

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Hollywood Darlings on Pop

For more infomation >> Hollywood Darlings on Pop

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A's Fans Celebrate 50th Anniversary Of Playing At Coliseum With Free Game - Duration: 2:05.

For more infomation >> A's Fans Celebrate 50th Anniversary Of Playing At Coliseum With Free Game - Duration: 2:05.

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'' Pibe '' Valderrama his prediction of James Rodriguez vs Real Madrid - Duration: 1:31.

Carlos 'the kid' Valderrama is happy quite when a footballer

Colombian is doing well in Europe. So he said after the

classification of the Munich bayern to the semifinal of the champions league with

James Rodríguez as a featured player inside the club and against nothing else and nothing

less than the real Madrid. before this encounter between the Colombian midfielder and

the Spanish club, the legendary player of the Colombian team said before a

local newspaper "she has papaya" I I imagine he already wants this to come

party because he knows that he will have a good revenge.

I'm going to the bayern munich for James, it would be good missing 2 minutes shot

free and that James gets to the angle. He added, as he would celebrate if it were

James Rodriguez. '' That if I celebrate it'''''clear I celebrate it and I celebrate it well

slowly, to be taken out of the stadium, and it will happen like that, with two minutes to go

free throw and he's going to put it in the corner and We are going to go crazy here in Colombia,

pointed the''pibe'' valderrama. On April 25 go receive the real madrid in the

Allianz Arena in Munich, and on May 1 will be the match of

back in santiago bernabéu. although James has stated that he does not see this

match against Real Madrid as a revenge a retaliation, obviously many

media have given this nuance and will be very aware of what can happen with

James in this meeting ...

For more infomation >> '' Pibe '' Valderrama his prediction of James Rodriguez vs Real Madrid - Duration: 1:31.

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BBB18: Ana Clara acusa Kaysar, resultado da final pode ser afetado II ANDYTRON3000 - Duration: 4:01.

For more infomation >> BBB18: Ana Clara acusa Kaysar, resultado da final pode ser afetado II ANDYTRON3000 - Duration: 4:01.

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Trump 'abençoa' conversações de paz com Coreia do Norte - Duration: 3:07.

For more infomation >> Trump 'abençoa' conversações de paz com Coreia do Norte - Duration: 3:07.

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BBB18: Verdade sobre Kaysar? Detalhe surpreende, confira II ANDYTRON3000 - Duration: 4:10.

For more infomation >> BBB18: Verdade sobre Kaysar? Detalhe surpreende, confira II ANDYTRON3000 - Duration: 4:10.

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Marcin Prokop jak młody Michał Szpak, a Magda Mołek śliczna jak Barbie. - Duration: 3:58.

For more infomation >> Marcin Prokop jak młody Michał Szpak, a Magda Mołek śliczna jak Barbie. - Duration: 3:58.

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Hrozivě zestárlá Whoopi Goldberg: Šedivé afro sestry v akci vypadá jakoobrovský - Duration: 1:31.

For more infomation >> Hrozivě zestárlá Whoopi Goldberg: Šedivé afro sestry v akci vypadá jakoobrovský - Duration: 1:31.

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ये है इश्क इश्क | Superhit Sufi Qawwali | Yeh Ishq Ishq Hai Ishq - Duration: 23:28.

Yeh Ishq Ishq Hai Ishq